Kinetics, catalysis and mechanism of methane steam reforming. Volume additive manufacturing of catalyst substrates for steammethane reforming michelle kramer 0 millie mckelvie 0 matthew watson 0 0 michelle kramer and matthew watson, chemical and process engineering, university of canterbury, christchurch, new zealand. Life cycle assessment of hydrogen production via natural. Membrane reactor, steam reforming, mathematical model. Methane steam reforming an overview sciencedirect topics. Equipment design and cost estimation for small modular. Nrel award aco544027, equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup and oxygen separation equipment. Currently, this process is the main route to obtain hydrogen and synthesis gas for ammonia and methanol. These models were used to simulate smallscale reactors which generate the hydrogen consumed in a stack of htpemfc. The long microchannel finned reactor design mitigates the potential for. Such hazard potential is inherent to the processing of toxic and flammable gases via high temperature reforming as practiced in hydrogen production. Model for steam reforming of ethanol using a catalytic. Methane steam reforming has been carried out in a pdru membrane reactor at 500600 c.
Comparison of catalyst geometries for methane steam. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. Development of a novel metal monolith catalyst for natural. Production of synthesis gas by steam methane reforming. Methane steam reforming in a pdru membrane reactor.
The aim of this study was to design and test labscale methanol steam reformers, and to employ the results of the experiments to develop a kinetic model for a new catalyst for methanol steam reforming at different conditions. The membrane reactor consisted of a pd6%ru tube of 100 mm wall thickness and commercial catalysts packed outside of the membrane. Pdf an industrial steam methane reformer optimization using. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Subsequently the modeling of the chemical reactions in, and of the heat transfer to the reactor tubes, will be discussed in section 3. Progresses in the preparation of coke resistant ni.
Steam methane reforming smr is a major hydrogen production process with more than 70 years of history. This thesis considers the design and operational feasibility of heat integrating two conventional industrial processes gasification and steam reforming of methane for application in polygeneration. Both methane conversion and hydrogen recovery are higher in. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. A fluidized bed membrane reactor for steam methane.
Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. The effects of operating parameters on methane conversion and h 2 yield are. Advanced modelling and optimisation of natural gas. Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. Natural gas is also a likely source of hydrogen for residential fuel cell systems, due to its wide availability and ease of conversion via steam methane reforming.
Methane steam reforming has been carried out in a pdru membrane reactor at 500600oc. Experimental and modeling studies of the methane steam. Catalyst design influences process variables such as pressure drop, conversion, and heat transfer. Download it once and read it on your kindle device, pc, phones or tablets. On the catalytic aspects of steammethane reforming a literature. Proceedings of the 4th international gas processing symposium, 2015. Steam methane reforming hydrogen production air liquide. This name is commonly retained even when other feedstocks e. It also accounts for transport through the membrane. The thermochemical watersplitting process offers a novel means for largescale. Pdf on the modeling of steam methane reforming researchgate. The methane conversion was significantly enhanced in the membrane reactor in which reaction equilibrium was shifted by selective permeation of hydrogen. Hydrogen from natural gas via steam methane reforming smr.
High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. The methane steam reforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion. The results show that larger cylinder radius can promote reforming reaction. Towards a thermal optimization of a methanesteam reforming reactor. Modeling of sorption enhanced steam methane reforming in. Production of hydrogen from natural gas is the most costeffective and simplest technology for commercial hydrogen generation. Water enters the furnace, producing steam at a very high temperature. The model describes mass and thermal dispersions for gas and solid phases. Hydrogen and syngas production and purification technologies. Both alternatives have been widely studied due to the use of mature techniques, i. The experimental studies of the steam reforming of methane were examined at various temperatures 773923 k and pressures 120 atm with a commercial nimgal2o4 catalyst in a hydrogen selective silicaalumina membrane reactor and compared with a packed bed reactor. The methane conversion to synthesis gas mixture of co and h 2 can be realized by different processes like the methane steam reforming msr with h 2 o 1234, dry methane reforming with. The methane conversion was significantly enhanced in the membrane reactor in which reaction equilibrium.
The steam reformer represents the core operating unit of most large scale hydrogen production facilities. Methane steam reforming consists in the reaction of methane and steam on a supported nickel catalyst to produce a mixture of h 2, co, co 2 and ch 4. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. The steam methane reforming process can be broken down into five distinct steps. The commercial steam methane reforming process is divided in two stages. Steam reforming of ethanol using a novel reactor configuration, called catalytic wall reactor, was successfully studied using comsol. Steam reforming of light hydrocarbons, especially natural gas, is an industrially important chemical reaction and a key step for producing hydrogen and syngas for ammonia and methanol production, hydrocracking and hydrotreating, oxoalcohol and fischertropsch synthesis and other essential processes in the petroleum and petrochemical industries. Steam reforming of methane for production of hydrogen and methanol. To this end, complex mathematical models that describe the integrated system are developed to study different design prospects and to determine. Steam reforming of methane in a synthesis gas from biomass. Comsol multiphysics was selected because is an ideal tool for coupling transport mechanisms mass, momentum, and heat transfer with chemical reactions. A 2d model and heat transfer mechanism are proposed to analyze and study oxidative steam reforming of methane osrm in a membrane reactor. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. The experimental study has been done in a plug flow reactor under a near atmospheric pressure 1.
The methanesteam reforming process is widely known as a conventional process for producing hydrogen 5. Methane reforming smr most common method of manufacturing hydrogen 90 95 vol% typical purity gasification partial oxidation produce synthesis gas syngas hydrogen recovery o pressure swing adsorption psa o membrane separation more expensive than steam reforming but. Use features like bookmarks, note taking and highlighting while reading production of synthesis gas by steam methane reforming. Pdf modeling and simulations of steam methane reforming smr process to produce hydrogen. Additive manufacturing of catalyst substrates for steam. Pdf steam methane reforming is an endothermic reaction which is considered. Steam reforming of methane is an extremely important process for the hydrogen and syngas production. Heat and mass transfer correlations for steam methane reforming. Taguchi design results, the optimum catalyst, in terms of hydrogen yield. Smr is a costeffective and energy efficient way of producing hydrogen.
In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted. C2pt catalyst process technology by gerard b hawkins managing director 2. Steam reacts with natural gas, producing hydrogen and carbon monoxide. A good catalyst design will have a low pressure drop to save on operating costs and have a high conversion.
In the reforming process of methane with steam, the dominant. The methane steamreforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion. In addition to the maturity of the technology, natural gas reforming is also the most economical among all hydrogen production pathways. In particular, we point our attention mainly toward the influence of the different retentate and permeate flux configurations on both methane conversion and hydrogen recovery. Comprehensive study of steam reforming of methane in. Effect of catalytic cylinders on autothermal reforming of. Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of natural gas. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. This work presents a conceptual design of a novel method to obtain hydrogen.
Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. Introduction the steam methane reforming process is the most widespread method for the hydrogen production. Design of process plant for producing hydrogen from steam. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Advanced modelling and optimisation of natural gas reforming. This physical modeling will be used in a lumped parameter model.
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